β-Hydride elimination is a reaction in which a metal- alkyl centre is converted into the corresponding metal- hydride - alkene. [1] β-Hydride elimination can also occur for many …

The most famous and ubiquitous type of β-elimination is β-hydride elimination, which involves the formation of a π bond and an M–H bond. Metal alkyls that contain β-hydrogens experience …

The reaction involves binding of isopropanol or 2-propanol to a metal ion, such as Ru (II) or Ru 2+. A deprotonation ensues, followed by elimination, and 2-propanone dissociates from the …

2015年3月31日 · Beta-hydride elimination is a common reaction in organometallic chemistry. The reaction is simply the transfer of a hydride (hydrogen atom) from the beta-position on a ligand …

2015年1月4日 · For Pd (0)-catalyzed reac-tions, control of β-hydride elimination is also a challenge for making coupling reactions more diversified. Different kinds of ligands were used …

Beta-hydride elimination is an reaction in which an alkyl group bonded to a metal centre is converted into the corresponding metal-bonded hydride and an alkene. [1] The alkyl must …

2016年8月17日 · β-Hydride elimination is a key organometallic transformation in which a metal alkyl complex is converted into a metal hydride olefin species (Chart 1). (1) It is the …

Beta-hydride elimination (β-Η) is the main decomposition pathway for transition metal-alkyl complexes, often hindering their use in cross-coupling reactions (Fig. 1a). 1,3,4 It is also an …

β-hydride elimination is a fundamental organometallic reaction where a metal complex eliminates a hydrogen atom and a ligand, typically resulting in the formation of an alkene. This reaction …

2011年8月25日 · Using density functional theory, we investigated detailed aspects of the quintessential organometallic process, β-hydride elimination (BHE). In general, we find that …